Profile (CV) of the research teaching staff

Sanz Miguel, Pablo José
Department: Departamento de Química Inorgánica
Field: Química Inorgánica
Faculty: Facultad de Ciencias

Research Institute: INSTITUTO DE SÍNTESIS QUÍMICA Y CATÁLISIS HOMOGÉNEA (ISQCH)
Group: E42_23R: Catálisis Homogénea por Compuestos Organometálicos
Academic position: Prof. Titular Univ.

Academic position
  • Coordinador de Máster Universitario en Química Molecular y Catálisis Homogénea
  • Vicedecano de Calidad de la Facultad de Ciencias
Email: psanz@unizar.es
ORCID number: 0000-0002-8220-6031
 
         

Journal articles

  • Polo, Alvaro; Gutiérrez Merino, Lara; Rodríguez, Ricardo; Sanz Miguel, Pablo J. Chirality at Metal in a Linear [Ag(NHC)2]+ Complex: Stereogenic C-Ag-C Axis, Atropisomerism and Role of p-p Interactions. CHEMISTRY - A EUROPEAN JOURNAL. 2024. DOI: 10.1002/chem.202403239

  • Ibáñez, Susana; Mejuto, Carmen; Cerón, Katherin; Sanz Miguel, Pablo J.; Peris, Eduardo. A corannulene-based metallobox for the encapsulation of fullerenes. CHEMICAL SCIENCE. 2024. DOI: 10.1039/d4sc03661a

  • Polo, Álvaro; Soriano-Jarabo, Alejandro; Rodríguez, Ricardo; Macías, Ramón; García-Orduña, Pilar; Sanz Miguel, Pablo J. Revisiting a natural wine salt: calcium (2R,3R)-tar­trate tetra­hydrate. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY. 2024. DOI: 10.1107/S2053229624008015

  • D’arcy, Kenneth; Schäfer, Tim; de Franco, Michele; Ricco, Raffaele; Gandin, Valentina; Sanz Miguel, Pablo J.; Montagner, Diego. Unusual tellurium(iv) mediated cyclisation diols into dihydroxazoles with potential anticancer activity. NEW JOURNAL OF CHEMISTRY. 2023. DOI: 10.1039/d3nj03186a

  • Diaw-Ndiaye, Fatou; Sanz Miguel, Pablo J.; Rodríguez, Ricardo; Macías, Ramón. The synthesis, characterization, and fluxional behavior of a hydridorhodatetraborane. MOLECULES. 2023. DOI: 10.3390/molecules28186462

  • Quintana, M.; Rodriguez-Rius, A.; Vellé, A.; Vives, S.; Sanz Miguel, P.J.; Triola, G. Dinuclear silver and gold bisNHC complexes as drug candidates for cancer therapy. BIOORGANIC AND MEDICINAL CHEMISTRY. 2022. DOI: 10.1016/j.bmc.2022.116814

  • Hermosilla, P.; García-Orduña, P.; Sanz Miguel, P. J.; Polo, V.; Casado, M. A. Nucleophilic Reactivity at a=CH Arm of a Lutidine-Based CNC/Rh System: Unusual Alkyne and CO2Activation; 35476902. INORGANIC CHEMISTRY. 2022. DOI: 10.1021/acs.inorgchem.2c00617

  • Lippert, B.; Sanz Miguel, P.J. Beyond sole models for the first steps of Pt-DNA interactions: Fundamental properties of mono(nucleobase) adducts of PtII coordination compounds. COORDINATION CHEMISTRY REVIEWS. 2022. DOI: 10.1016/j.ccr.2022.214566

  • Lippert, Bernhard; Sanz Miguel, Pablo J. Assembly of nucleobases into rings and cages via metal ions. JOURNAL OF COORDINATION CHEMISTRY. 2022. DOI: 10.1080/00958972.2022.2105144

  • Vellé, Alba; Rodríguez-Santiago, Luis; Sodupe, Mariona; Sanz Miguel, Pablo J. Enhanced Metallophilicity in Metal-Carbene Systems: Stronger Character of Aurophilic Interactions in Solution. CHEMISTRY - A EUROPEAN JOURNAL. 2020. DOI: 10.1002/chem.201904507

  • Lippert, Bernhard; Sanz Miguel, Pablo J. Merging Metal-Nucleobase Chemistry With Supramolecular Chemistry. ADVANCES IN INORGANIC CHEMISTRY. 2018. DOI: 10.1016/bs.adioch.2017.11.002

  • Pérez, Sandra; Sanz, Pablo J.; Macías, Ramón. Decaborane anion tautomerism: ion pairing and proton transfer control. DALTON TRANSACTIONS. 2018. DOI: 10.1039/c8dt00610e

  • Lippert, B.; Sanz Miguel, P.J. Comparing PtII- and PdII-nucleobase coordination chemistry: Why PdII not always is a good substitute for PtII. INORGANICA CHIMICA ACTA. 2018. DOI: 10.1016/j.ica.2017.06.047

  • Silaghi-Dumitrescu, R.; Mihály, B.; Mihály, T.; Attia, A. A. A.; Sanz Miguel, P. J.; Lippert, B. The exocyclic amino group of adenine in PtII and PdII complexes: a critical comparison of the X-ray crystallographic structural data and gas phase calculations. JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY. 2017. DOI: 10.1007/s00775-017-1448-1

  • Vellé, A.; Maguire, R.; Kavanagh, K.; Sanz Miguel, P.J.; Montagner, D. Steroid–AuI–NHC Complexes: Synthesis and Antibacterial Activity. CHEMMEDCHEM. 2017. DOI: 10.1002/cmdc.201700257

  • Vellé, A.; Cebollada, A.; Macías, R.; Iglesias, M.; Gil-Moles, M.; Sanz Miguel, P.J. From Imidazole toward Imidazolium Salts and N-Heterocyclic Carbene Ligands: Electronic and Geometrical Redistribution. ACS OMEGA. 2017. DOI: 10.1021/acsomega.7b00138

  • Aznarez, F.; Sanz Miguel, P. J.; Tan, T. T. Y.; Hahn, F. E. Preparation of Rhodium(III) Di-NHC Chelate Complexes Featuring Two Different NHC Donors via a Mild NaOAc-Assisted C-H Activation. ORGANOMETALLICS. 2016. DOI: 10.1021/acs.organomet.5b00993

  • Lippert, B.; Sanz Miguel, P. J. More of a misunderstanding than a real mismatch? Platinum and its affinity for aqua, hydroxido, and oxido ligands. COORDINATION CHEMISTRY REVIEWS. 2016. DOI: 10.1016/j.ccr.2016.03.008

  • Iturmendi, Amaia; Sanz Miguel, Pablo J.; Popoola, Saheed A.; Al-Saadi, Abdulaziz A.; Iglesias, Manuel; Oro, Luis A. Dimethylphosphinate bridged binuclear Rh(i) catalysts for the alkoxycarbonylation of aromatic C-H bonds. DALTON TRANSACTIONS. 2016. DOI: 10.1039/c6dt03010f

  • Iturmendi, Amaia; García, Nestor; Jaseer, E.A; Munárriz, Julen; Sanz Miguel, Pablo J.; Polo, Victor; Iglesias, Manuel; Oro, Luis A. N-Heterocyclic olefins as ancillary ligands in catalysis: A study of their behaviour in transfer hydrogenation reactions. DALTON TRANSACTIONS. 2016. DOI: 10.1039/c6dt02571d

  • Aznarez, Francisco; Iglesias, Manuel; Hepp, Alexander; Veit, Benjamin; Sanz Miguel, Pablo J.; Oro, Luis A.; Jin, Guoxin; Hahn, F.Ekkehardt. Iridium(III) Complexes Bearing Chelating Bis-NHC Ligands and Their Application in the Catalytic Reduction of Imines. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2016. DOI: 10.1002/ejic.201600922

  • Velle, A.; Cebollada, A.; Lippert, B.; Miguel, P.J.S. Topology of metallacalix[4]arenes with uracil and cytosine ligands: favorable and unfavorable assemblies. NEW JOURNAL OF CHEMISTRY. 2016. DOI: 10.1039/c6nj00772d

  • Cebollada, A.; Vellé, A.; Sanz Miguel, P. J. Hirshfeld and DFT analysis of the N-heterocyclic carbene proligand methylenebis(N-butylimidazolium) as the acetonitrile-solvated diiodide salt. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY. 2016. DOI: 10.1107/S2053229616006781

  • Yin-Bandur, L.; Sanz Miguel, P. J.; Rodríguez-Santiago, L.; Sodupe, M.; Berghaus, M.; Lippert, B. Multiple Condensation Reactions Involving PtII/PdII-OH2, Pt-NH3, and Cytosine-NH2 Groups: New Twists in Cisplatin-Nucleobase Chemistry. CHEMISTRY - A EUROPEAN JOURNAL. 2016. DOI: 10.1002/chem.201602244

  • Lippert, B.; Sanz Miguel, P. J. The Renaissance of Metal-Pyrimidine Nucleobase Coordination Chemistry. ACCOUNTS OF CHEMICAL RESEARCH. 2016. DOI: 10.1021/acs.accounts.6b00253

  • Siebel, S.; Dammann, C.; Sanz Miguel, P. J.; Drewello, T.; Kampf, G.; Teubner, N.; Bednarski, P. J.; Freisinger, E.; Lippert, B. Analogues of Cis- and Transplatin with a Rich Solution Chemistry: Cis-[PtCl2(NH3)(1-MeC-N3)] and trans-[PtI2(NH3)(1-MeC-N3)]. CHEMISTRY - A EUROPEAN JOURNAL. 2015. DOI: 10.1002/chem.201502691

  • Iglesias, M.; Iturmendi, A.; Sanz Miguel, P. J.; Polo, V.; Pérez-Torrente, J. J.; Oro, L. A. Tuning PCP-Ir complexes: The impact of an N-heterocyclic olefin. CHEMICAL COMMUNICATIONS. 2015. DOI: 10.1039/c5cc04287a

  • García, N.; Jaseer, E.A.; Munarriz, J.; Sanz Miguel, P.J.; Polo, V.; Iglesias, M.; Oro, L.A. An insight into transfer hydrogenation reactions catalysed by iridium(iii) bis-n-heterocyclic carbenes. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2015. DOI: 10.1002/ejic.201500853

  • Aliaga-Lavrijsen, Mélanie; Iglesias, Manuel; Cebollada, Andrea; Garcés, Karin; García, Nestor; Sanz Miguel, Pablo J.; Fernández-Alvarez, Francisco J.; Pérez-Torrente, Jesús J.; Oro, Luis A. Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis- N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups. ORGANOMETALLICS. 2015. DOI: 10.1021/om5011726

  • Iglesias,M.; Aliaga-Lavrijsen,M.; Miguel,P. J. S.; Fernández-Alvarez,F. J.; Pérez-Torrente,J. J.; Oro,L. A. Preferential a -hydrosilylation of terminal alkynes by bis-N-heterocyclic carbene rhodium(III) catalysts. ADVANCED SYNTHESIS AND CATALYSIS. 2015. DOI: 10.1002/adsc.201400673

  • Ibáñez,S.; Mihály,B.; Sanz Miguel,P. J.; Steinborn,D.; Pretzer,I.; Hiller,W.; Lippert,B. The challenge of deciphering linkage isomers in mixtures of oligomeric complexes derived from 9-methyladenine and trans-(NH3)2PtII units. CHEMISTRY - A EUROPEAN JOURNAL. 2015. DOI: 10.1002/chem.201406378

  • Cebollada, A.; Vellé, A.; Iglesias, M.; Fullmer, L. B.; Goberna-Ferrõn, S.; Nyman, M.; Sanz Miguel, P. J. Direct X-ray scattering evidence for metal-metal interactions in solution at the molecular level. ANGEWANDTE CHEMIE (INTERNATIONAL ED.). 2015. DOI: 10.1002/anie.201505736

  • Lippert, Bernhard; Fonseca Guerra, Célia; Sanz Miguel, Pablo J.; Cebollada, Andrea; Bickelhaupt, F. Matthias. On the structural variability of exocyclic amino groups in free and metalated cytosine nucleobases. JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY. 2014. DOI: 10.1007/s00775-014-1155-0

  • Amo-Ochoa,P.; Castillo,O.; Guijarro,A.; Sanz Miguel,P. J.; Zamora,F. Supramolecular architectures based on 6-purinethione complexes. INORGANICA CHIMICA ACTA. 2014. DOI: 10.1016/j.ica.2013.09.054

  • Vellé, A.; Cebollada, A.; Iglesias, M.; Sanz Miguel, P. J. Argentophilicity as Essential Driving Force for a Dynamic Cation-Cation Host-Guest System: [Ag(acetonitrile)2]+ ¿ [Ag2(bis-NHC)2]2+ (NHC = N-heterocyclic carbene). INORGANIC CHEMISTRY. 2014. DOI: 10.1021/ic501715h

  • Fonseca Guerra,C.; Sanz Miguel,P. J.; Cebollada,A.; Bickelhaupt,F. M.; Lippert,B. Rationalizing the structural variability of the exocyclic amino groups in nucleobases and their metal complexes: Cytosine and adenine. CHEMISTRY - A EUROPEAN JOURNAL. 2014. DOI: 10.1002/chem.201403066

  • Khutia, A.; Shen, W. -Z; Das, N.; Sanz Miguel, P. J.; Lippert, B. Rationalizing the formation and versatility of multinuclear metal complexes of bis(1-methyluracil-5-yl)methane as hybrids between classical calix[n]arenes and metallacalixaromatics. INORGANICA CHIMICA ACTA. 2014. DOI: 10.1016/j.ica.2014.01.020

  • Alegre-Requena, J.; Marqués-López, E.; Sanz Miguel, P. J.; Herrera, R. P. Organocatalytic enantioselective hydrophosphonylation of aldehydes. ORGANIC & BIOMOLECULAR CHEMISTRY. 2014. DOI: 10.1039/c3ob42403k

  • Albertí, F. M.; Rodríguez-Santiago, L.; Sodupe, M.; Mirats, A.; Kaitsiotou, H.; Sanz Miguel, P. J.; Lippert, B. Mixed adenine/guanine quartets with three trans-a2Pt II (a=NH3 or MeNH2) cross-links: Linkage and rotational isomerism, base pairing, and loss of NH3. CHEMISTRY - A EUROPEAN JOURNAL. 2014. DOI: 10.1002/chem.201304686

  • Sanz Miguel, Pablo J.; Cebollada, Andrea; Vellé, Alba. M–Purine(C8) constructs and their potential applications in catalysis. JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY. 2014. DOI: 10.1007/s00775-014-1159-9

  • Lázaro, G.; Iglesias, M.; Fernández-Alvarez, F. J.; Sanz Miguel, P. J.; Pérez-Torrente, J. J.; Oro, L. A. Synthesis of Poly(silyl ether)s by Rhodium(I)-NHC Catalyzed Hydrosilylation: Homogeneous versus Heterogeneous Catalysis. CHEMCATCHEM. 2013. DOI: 10.1002/cctc.201200309

  • Von Grebe, P.; Suntharalingam, K.; Vilar, R.; Sanz Miguel, P. J.; Herres-Pawlis, S.; Lippert, B. A conformationally flexible dinuclear PtII complex with differential behavior of its two states toward quadruplex DNA. CHEMISTRY - A EUROPEAN JOURNAL. 2013. DOI: 10.1002/chem.201301400

  • Galstyan,A.; Sanz Miguel,P. J.; Weise,K.; Lippert,B. Discrete and polymeric heteronuclear constructs derived from triangular 2,2'-bipyrazine complexes of cis-a2PtII (with a = NH3 or a2 = en). DALTON TRANSACTIONS. 2013. DOI: 10.1039/c3dt51589c

  • Iglesias, M.; Sanz Miguel, P. J.; Polo, V.; Fernández-Alvarez, F. J.; Pérez-Torrente, J. J.; Oro, L. A. An Alternative Mechanistic Paradigm for the ß-Z Hydrosilylation of Terminal Alkynes: The Role of Acetone as a Silane Shuttle. CHEMISTRY - A EUROPEAN JOURNAL. 2013. DOI: 10.1002/chem.201303063

  • Kozma, A.; Ibáñez, S.; Silaghi-Dumitrescu, R.; Sanz Miguel, P. J.;Gupta,D.; Lippert, B. 7-Methylguanine: Protonation, formation of linkage isomers with trans-(NH 3) 2Pt II, and base pairing properties. DALTON TRANSACTIONS. 2012. DOI: 10.1039/c2dt12228f

  • Mihály, T.; Garijo, M.; Albertí, F.M.; Sanz Miguel, P.J.; Lippert, B. Multiple Metal Binding to the 9-Methyladenine Model Nucleobase Involving N1, N6, and N7: Discrete Di- and Trinuclear Species with Different Combinations of Monofunctional PdII and PtII Entities. INORGANIC CHEMISTRY. 2012. DOI: 10.1021/ic301681f

  • Pérez, A.; Espinosa, L.A.; Azani, Mohammad-Reza; Guijarro, A.; Sanz Miguel, P.J.; Givaja, G.; Castillo, O.; Mas-Ballesté, R.; Zamora, F.; Rubio, A. Supramolecular Assembly of Diplatinum Species through Weak PtII...PtII Intermolecular Interactions: A Combined Experimental and Computational Study. CHEMISTRY - A EUROPEAN JOURNAL. 2012. DOI: 10.1002/chem.201201962

  • Lalrempuia, R.; Iglesias, M.; Polo, V.; Sanz Miguel, P.J.; Fernández-Alvarez, F.J.; Pérez-Torrente, J.J.; Oro, L.A. Effective Fixation of CO2 by Iridium-Catalysed Hydrosilylation. ANGEWANDTE CHEMIE (INTERNATIONAL ED.). 2012. DOI: 10.1002/ange.201206165

  • Yin,L.; Sanz Miguel,P. J.; Hiller,W.; Lippert,B. Different Rotamer States of Cytosine Nucleobases in Heteronuclear PtPd-, PtPd2, and Pt2Pd2Ag Complexes Derived from [Pt(2,2'-bpy)(1-MeC-N3)2]2+ (1-MeC = 1-Methylcytosine): First Examples of Species with Head–Head Oriented 1-MeC– Ligands. INORGANIC CHEMISTRY. 2012. DOI: 10.1021/ic3005097

  • Iglesias, Manuel; Pérez-Nicolás, María; Sanz Miguel, Pablo J.; Polo Ortiz, Victor; Fernández-Alvarez, Francisco J.; Pérez-Torrente, Jesús J.; Oro, Luis A. . A synthon for a 14-electron Ir( III) species: catalyst for highly selective b -( Z ) hydrosilylation of terminal alkynes. CHEMICAL COMMUNICATIONS. 2012. DOI: 10.1039/C2CC34931K

  • Von Grebe,P.; Sanz Miguel,P. J.; Lippert,B. Flat vs. Folded Chelate Rings in cis-PtIIa2 (a = NH3, a2 = en, a2 = 2, 2'-bpy) Complexes of Twofold Substituted Diazine Ligands. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 2012. DOI: 10.1002/zaac.201200306

  • Brandi-Blanco, P.;Sanz Miguel, P. J.;Lippert, B. Expected and unconventional Ag + binding modes in heteronuclear Pt,Ag coordination polymers derived from trans-[Pt(methylamine) 2(pyrazole) 2] 2+. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2012. DOI: 10.1002/ejic.201101197

  • Chakraborty,S.;Sanz Miguel,P. J.;Albertí,F. M.;Das,N. Construction of preorganized uracil based polytopic tectons for hydrogen-bonded supramolecular architectures. JOURNAL OF MOLECULAR STRUCTURE. 2012. DOI: 10.1016/j.molstruc.2012.02.012

  • Galstyan, A.; Sanz Miguel, P. J.; Wolf, J.; Freisinger, E. ; Lippert, B. Discrete Molecular Squares {[(en)M(CN)]4}4+ Derived from [(en)M(CN)2] (M = PtII, PdII). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2011. DOI: 10.1002/ejic.201001216

  • Khutia, A.; Sanz Miguel, P. J. ; Lippert, B. "directed" assembly of metallacalix[n]arenes with pyrimidine nucleobase ligands of low symmetry: Interchanging metals in mixed-metal metallacalix[4]arenes and incorporating additional metals at the exocyclic groups. CHEMISTRY - A EUROPEAN JOURNAL. 2011. DOI: 10.1002/chem.201002723

  • Galstyan, A.; Sanz Miguel, P. J.; Lippert, B. A "directed" approach toward a cationic molecular square containing four isonicotinamidate ligands and (4 + 2) (en)PtII metal entities. INORGANICA CHIMICA ACTA. 2011. DOI: 10.1016/j.ica.2011.02.041

  • Ibáñez, S.; Albertí, F. M.; Sanz Miguel, P. J.; Lippert, B. Exploring the metal coordination properties of the pyrimidine part of purine nucleobases: Isomerization reactions in heteronuclear Pt II/PdII of 9-methyladenine. INORGANIC CHEMISTRY. 2011. DOI: 10.1021/ic201548k

  • Lippert, B.; Sanz Miguel, P. J. Metallatriangles and metallasquares: The diversity behind structurally characterized examples and the crucial role of ligand symmetry. CHEMICAL SOCIETY REVIEWS. 2011. DOI: 10.1039/c1cs15090a

  • Galstyan, A.;Shen, W-Z; Freisinger, E.; Alkam, H.; Hiller, W.; Sanz Miguel, P. J.; Schürmann, M.; Lippert, B. Supramolecular Isomerism of 2,2'-Bipyrazine Complexes with cis-(NH3)2PtII: Ligand Rotational State and Sequential Orientation Determine the 3D Shape of Metallacycles. CHEMISTRY - A EUROPEAN JOURNAL. 2011. DOI: 10.1002/chem.201101381

  • Müller, B.;Shen, W-Z; Sanz Miguel, P. J.; Albertí, F. M.; Van Der Wijst, T.; Noguera, M.; Rodríguez-Santiago, L.; Sodupe, M.; Lippert, B. PtII coordination to N1 of 9-methylguanine: Why it facilitates binding of additional metal ions to the purine ring. CHEMISTRY - A EUROPEAN JOURNAL. 2011. DOI: 10.1002/chem.201101148

  • Cubo, L.; Hambley, T. W.; Sanz Miguel, P. J.; Carnero, A.; Navarro-Ranninger, C.; Quiroga, A. G. The preparation and characterization of trans-platinum(IV) complexes with unusually high cytotoxicity. DALTON TRANSACTIONS. 2011. DOI: 10.1039/c0dt00565g

  • Khutia, Anupam; Sanz Miguel, Pablo J.; Lippert, Bernhard. "Directed" assembly of metallacalix[n]arenes with pyrimidine nucleobase ligands of low symmetry: Metallacalix[n]arene derivatives of cis-[a2M(cytosine-N3)2]2+ (M=PtII, PdII; N=4 and 6). CHEMISTRY - A EUROPEAN JOURNAL. 2011. DOI: 10.1002/chem.201002722

  • Khutia, A.; Sanz Miguel, P. J.; Lippert, B. Molecular architectures derived from metal ions and the flexible 3,3'-bipyridine ligand. Unexpected dimer with Hg(II). BIOINORGANIC CHEMISTRY AND APPLICATIONS. 2010. DOI: 10.1155/2010/169054

  • Khutia, A.; Sanz Miguel, P.; Lippert, B. Influence of PtII and PdII coordination on the equilibrium of 2,2'-dipyridylketone (dpk) with its hydrated gem-diol form (dpk·H2O). INORGANICA CHIMICA ACTA. 2010. DOI: 10.1016/j.ica.2010.02.035

  • Mas-Ballesté, R.; Guijarro, A.; González-Prieto, R.; Castillo, O.; Sanz Miguel, P. J.; Zamora, F. S–S bond reactivity in metal-perthiocarboxylato compounds. DALTON TRANSACTIONS. 2010. DOI: 10.1039/b915518j

  • Guijarro, A.; Castillo, O.; Welte, L.; Calzolari, A.; Sanz Miguel, P. J.; Gómez-García, C. J.; Olea, D.; Di Felice, R.; Gómez-Herrero, J.; Zamora, F. Conductive nanostructures of MMX chains. ADVANCED FUNCTIONAL MATERIALS. 2010. DOI: 10.1002/adfm.200901901

  • Sanz Miguel, P. J.; Roitzsch, M.; Yin, L.; Lax, P. M.; Holland, L.; Krizanovic, O.; Lutterbeck, M.; Schürmann, M.; Fusch, E. C.; Lippert, B. On the many roles of NH3 ligands in mono- and multinuclear complexes of platinum. DALTON TRANSACTIONS. 2009. DOI: 10.1039/b916537a

  • Sanz Miguel, Pablo J.; Yin, Lu; Shen, Wei-Zheng; Lippert, Bernhard. On the reactivity of ammonia ligands of cisplatin: dual affinity of a cis-(NH3)2PtII nucleobase complex for both anions and cations. JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY. 2009. DOI: 10.1007/s00775-009-0518-4

  • Brandi-Blanco, P.; Sanz Miguel, P. J.; Müller, B.; Gil Bardají, E.; Willermann, M.; Lippert, B. Expanding the pH range of metal-nucleobase complexes for acid-base chemistry: Properties of bis(guanine) complexes of (bpy) PtII with either two major or major and minor tautomers bonded simultaneously. INORGANIC CHEMISTRY. 2009. DOI: 10.1021/ic900176c

  • Yin, Lu; Sanz Miguel, Pablo J.; Shen, Wei-Zheng; Lippert, Bernhard. PdII-catalyzed condensation of a mononuclear Pt-nucleobase complex to its head-tail dimer: Characterization of a key intermediate and an end product. CHEMISTRY - A EUROPEAN JOURNAL. 2009. DOI: 10.1002/chem.200902245

  • Zamora, F.; Amo-Ochoa, P.; Sanz Miguel, P. J.; Castillo, O. From metal-nucleobase chemistry towards molecular wires. INORGANICA CHIMICA ACTA. 2009. DOI: 10.1016/j.ica.2008.02.029

  • Mas-Ballesté, R.; Castillo, O.; Sanz Miguel, P. J.; Olea, D.; Gómez-Herrero, J.; Zamora, F. Towards molecular wires based on metal-organic frameworks. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2009. DOI: 10.1002/ejic.200801090

  • Mateo-Martí, E.; Welte, L.; Amo-Ochoa, P.; Sanz Miguel, P. J.; Gómez-Herrero, J.; Martín-Gago, J. A.; Zamora, F. Direct evidence of nanowires formation from a Cu(I) coordination polymer. CHEMICAL COMMUNICATIONS. 2008. DOI: 10.1039/b711416h

  • Quiroga, A. G.; Cubo, L.; Sanz Miguel, P. J.; Moneo, V.; Carnero, A.; Navarro-Ranninger, C. Isolation of an intermediate in the platination of p-nitroacetophenone 4-Methylthiosemicarbazone: Potential application as an antitumor drug. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2008. DOI: 10.1002/ejic.200800003

  • Delgado, S.; Sanz Miguel, P. J.; Priego, J. L.; Jiménez-Aparicio, R.; Gómez-García, C. J.; Zamora, F. A conducting coordination polymer based on assembled Cu9 cages. INORGANIC CHEMISTRY. 2008. DOI: 10.1021/ic801314s

  • Kampf, G.; Sanz Miguel, P. J.; Morell Cerdà, M.; Willermann, M.; Schneider, A.; Lippert, B. Reactivity of ammonia ligands of the antitumor agent cisplatin: a unique dodecanuclear Pt4,Pd4,Ag4 platform for four cytosine model nucleobases. CHEMISTRY - A EUROPEAN JOURNAL. 2008. DOI: 10.1002/chem.200800586

  • Guijarro, A.; Castillo, O.; Calzolari, A.; Sanz Miguel, P. J.; Gómez-García, C. J.; Di Felice, R.; Zamora, F. Electrical conductivity in platinum-dimer columns. INORGANIC CHEMISTRY. 2008. DOI: 10.1021/ic801211m

  • Amo-Ochoa, P.; Castillo, O.; Sanz Miguel, P. J.; Zamora, F. Unusual dimeric Zn(II)-cytosine complexes: New models of the interaction of Zn(II) with DNA and RNA. JOURNAL OF INORGANIC BIOCHEMISTRY. 2008. DOI: 10.1016/j.jinorgbio.2007.07.036

  • Düpre, N.; Shen, W.-Z.; Sanz Miguel, P. J.; Müller, J. 3,5-Di-p-toluoyl-1,2-dideoxy-ß-1-(imidazol-1-yl)-D-ribofuranose. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. 2007. DOI: 10.1107/S1600536807056760

  • Alexandre, S. S.; Soler, J. M.; Sanz Miguel, P. J.; Nunes, R. W.; Yndurain, F.; Gómez-Herrero, J.; Zamora, F. Design of molecular wires based on one-dimensional coordination polymers. APPLIED PHYSICS LETTERS. 2007. DOI: 10.1063/1.2737371

  • Amo-Ochoa, P.; Sanz Miguel, P. J.; Castillo, O.; Zamora, F. An unusual triple parallel interpenetrated 2D Cu-polymer, with a 3D triple interpenetration via H-bonding. CRYSTENGCOMM. 2007. DOI: 10.1039/b709457d

  • Amo-Ochoa, P.; Givaja, G.; Sanz Miguel, P. J.; Castillo, O.; Zamora, F. Microwave assisted hydrothermal synthesis of a novel Cu(I)-sulfate-pyrazine MOF. INORGANIC CHEMISTRY COMMUNICATIONS. 2007. DOI: 10.1016/j.inoche.2007.04.024

  • Amo-Ochoa, P.; Sanz Miguel, P. J.; Castillo, O.; Sabat, M.; Lippert, B.; Zamora, F. Interguanine hydrogen-bonding patterns in adducts with water and Zn-purine complexes (purine is 9-methyladenine and 9-methylguanine). Unexpected preference of Zn(II) for adenine-N7 over guanine-N7. JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY. 2007. DOI: 10.1007/s00775-007-0206-1

  • Willermann, M.; Mulcahy, C.; Sigel, R. K. O.; Morell Cerdà, M.; Freisinger, E.; Sanz Miguel, P. J.; Roitzsch, M.; Lippert, B. Pyrazine as a Building Block for Molecular Architectures with PtII. INORGANIC CHEMISTRY. 2006. DOI: 10.1021/ic051966k

  • Sanz Miguel, P. J.; Lax, P.; Lippert, B. (Dien)MII (M = Pd, Pt) and (NH3)3PtII complexes of 1-methylcytosine: Linkage and rotational isomerism, metal-promoted deamination, and pathways to dinuclear species. JOURNAL OF INORGANIC BIOCHEMISTRY. 2006. DOI: 10.1016/j.jinorgbio.2006.02.017

  • Sanz Miguel, P. J.; Lippert B. Cationic tetrakis(nucleobase)complexes of PtII as metalloligands and potential building blocks for molecular architectures. DALTON TRANSACTIONS. 2005. DOI: 10.1039/B502251G

  • Roitzsch, M.; Garijo Añorbe, M.; Sanz Miguel, P. J.; Müller, B.; Lippert, B. The role of intramolecular hydrogen bonding on nucleobase acidification following metal coordination: Possible implications of an ‘‘indirect’’ role of metals in acid–base catalysis of nucleic acids. JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY. 2005. DOI: 10.1007/s00775-005-0030-4

  • Amo-Ochoa, P.; Sanz Miguel, P. J.; Lax, P.; Alonso, I.; Roitzsch, M.; Zamora, F.; Lippert, B. Models of putative (AH)G(AH)G nucleobase quartets. ANGEWANDTE CHEMIE (INTERNATIONAL ED.). 2005. DOI: 10.1002/anie.200500896

  • Sanz Miguel, P. J.; Lax, P.; Willermann, M.; Lippert, B. Coexistence of major and minor tautomers of 1-methylcytosine (1-MeC) in a single metal complex, trans-Pt(1-MeC-N3)(1-MeC-N4)X2 (X = Cl, I): metal migration N3¿N4 at acidic pH. INORGANICA CHIMICA ACTA. 2004. DOI: 10.1016/j.ica.2004.07.009

  • Sponer, J. E.; Sanz Miguel, P. J.; Rodríguez-Santiago, L.; Erxleben, A.; Krumm, M.; Sodupe, M.; Sponer, J.; Lippert, B. Metal-mediated deamination of cytosine: experiment and DFT calculations. ANGEWANDTE CHEMIE (INTERNATIONAL ED.). 2004. DOI: 10.1002/anie.200460107

  • Müller, J.; Freisinger, E.; Sanz Miguel, P. J.; Lippert, B. Diplatinum(III) complexes with four bridging 1-methylcytosinato nucleobases derived from a mononuclear trans-(NH3)2PtII complex and CuII. INORGANIC CHEMISTRY. 2003. DOI: 10.1021/ic0343152

Conference presentations

  • Rubio-Pérez, Laura; Iglesias, Manuel; Munárriz, Julen; Polo, Víctor; Sanz Miguel, Pablo J.; Pérez-Torrente, Jesús J.; Oro, Luis A. A bimetallic iridium(ii) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1, 3-bis(2, 6-diisopropylphenylimidazol-2-ylidene)). CHEMICAL COMMUNICATIONS. 2015. DOI: 10.1039/c5cc03296b

  • Albertí, F. M.; Zielinski, W.; Morell Cerda, M.; Sanz Miguel, P. J.; Troeppner, O.; Ivanovic-Burmazovic, I.; Lippert, B. Stepwise coordination of PtII-180°and PdII- 90°metal fragments to the purine nucleobase 9-methylhypoxanthine affords a closed octadecanuclear Pt6Pd12 cluster. CHEMISTRY - A EUROPEAN JOURNAL. 2013. DOI: 10.1002/chem.201300446

  • Albertí,F. M.; Mihály,T.; Lippert,B.; Sanz Miguel,P. J. Unsupported single-walled water cluster nanotube: A novel hydrogen bonding pattern for water organization. CRYSTENGCOMM. 2012. DOI: 10.1039/c2ce25647a

  • Brandi-Blanco, P.; Sanz Miguel, P. J. ; Lippert, B. Coordination of two different metal ions as reason for N-chirality in -amide complexes. DALTON TRANSACTIONS. 2011. DOI: 10.1039/c1dt10585j

  • Ibáñez, S.; Albertí, F. M.; Sanz Miguel, P. J.; Lippert, B. C3-symmetric Pt3Pd3 purine vases based on a metal coordination motif involving the pyrimidinic N1 and N3 sites. CHEMISTRY - A EUROPEAN JOURNAL. 2011. DOI: 10.1002/chem.201101414

  • Holland, L.;Shen, W-Z.; Von Grebe, P.; Sanz Miguel, P. J.; Pichierri, F.; Springer, A.; Schalley, C. A.; Lippert, B. A neutral Pt3 stack unsupported by any bridging ligand. DALTON TRANSACTIONS. 2011. DOI: 10.1039/c0dt01408g

  • Montagner, D.; Sanz Miguel, P. J. Unique Pt5 metallacycle: [PtIICl(pyrrolidinedithiocarbamate)]5. DALTON TRANSACTIONS. 2011. DOI: 10.1039/c1dt11475a

  • Suntharalingam, K.; Gupta, D.; Sanz Miguel, P. J.; Lippert, B.; Vilar, R. Synthesis, structural characterisation and quadruplex DNA binding studies of a new gold(III) pyrazolylpyridine complex. CHEMISTRY - A EUROPEAN JOURNAL. 2010. DOI: 10.1002/chem.200903501

  • Amo-Ochoa, P.; Welte, L.; González-Prieto, R.; Sanz Miguel, P. J.; Gómez-García, C. J.; Mateo-Martí, E.; Delgado, S.; Gómez-Herrero, J.; Zamora, F. Single layers of a multifunctional laminar Cu(I,II) coordination polymer. CHEMICAL COMMUNICATIONS. 2010. DOI: 10.1039/b919647a

  • Galstyan, A.; Sanz Miguel, P. J.; Lippert B. Electrostatics plus O-p interactions rather than “directed” hydrogen bonding keep SO42– in a triangular Pt3Pd3-2,2'-bipyrazine host. CHEMISTRY - A EUROPEAN JOURNAL. 2010. DOI: 10.1002/chem.201000500

  • Khutia, A.; Sanz Miguel, P. J.; Lippert, B. Isomerism with metallacalix[4]arenes of the non-symmetrical pyrimidine nucleobase cytosine: How connectivity and rotamer state determine the topology of multinuclear derivatives. INORGANIC CHEMISTRY. 2010. DOI: 10.1021/ic100794s

  • Galstyan, A.; Sanz Miguel, P. J.; Lippert B. [NO3¿{(en)Pt(2,2'-bpz)}3]NO3(SO4)2: Snapshot of nitrate insertion into a cationic Pt3 metallacycle or simply a packing effect?. DALTON TRANSACTIONS. 2010. DOI: 10.1039/C0DT00463D

  • Das, N.; Sanz Miguel, P. J.; Khutia, A.; Lazar, M.; Lippert, B. Hybrids between classical and metallacalix[4]arenes based on uracil and cis-PtIIL2 entities (L = P(Ph)3 or L2 = 2,2'-bipyridine). DALTON TRANSACTIONS. 2009. DOI: 10.1039/b916178n

Scientific chapters



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