Perfil (CV) del personal docente investigador

Buil Juan, María Luisa
Departamento: Departamento de Química Inorgánica
Área: Química Inorgánica
Centro: Facultad de Ciencias

Instituto: INSTITUTO DE SÍNTESIS QUÍMICA Y CATÁLISIS HOMOGÉNEA (ISQCH)
Grupo: ORGANOMETÁLICOS Y CATÁLISIS

Tramos de investigación
  • Sexenio CNEAI. 01/01/23
  • Sexenio CNEAI. 01/01/20. (3)
  • ACPUA. 19/06/18
  • ACPUA. 25/04/12
  • ACPUA. 31/10/06. (2)
Categoría profesional: Prof. Titular Univ.

Cargos
  • Coordinadora del Programa de Doctorado en Química Inorgánica
  • Profesora Secretaria del Departamento de Química Inorgánica
Teléfono móvil: 630378484
Correo electrónico: mbuil@unizar.es
ORCID: 0000-0002-3284-1053

Líneas de investigación
  • Química organometálica
  • Homogénea

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Artículos

  • Benítez, María; Buil, María L.; Esteruelas, Miguel A.; López, Ana M.; Martín-Escura, Cristina; Oñate, Enrique. C–H, N–H, and O–H Bond Activations to Prepare Phosphorescent Hydride-Iridium(III)-Phosphine Emitters with Photocatalytic Achievement in C–C Coupling Reactions. INORGANIC CHEMISTRY. 2024. DOI: 10.1021/acs.inorgchem.4c00115

  • Buil, María L.; Esteruelas, Miguel A.; Oñate, Enrique; Picazo, Nieves R. Unequivocal characterization of an osmium complex with a terminal sulfide ligand and its transformation into hydrosulfide and methylsulfide. INORGANIC CHEMISTRY. 2024. DOI: 10.1021/acs.inorgchem.4c00596

  • Buil, M. L.; Esteruelas, M. A.; Oñate, E.; Rodríguez Picazo, N. Osmathiazole ring: Extrapolation of an aromatic purely organic system to organometallic chemistry. ORGANOMETALLICS. 2023. DOI: 10.1021/acs.organomet.2c00631

  • Adamovich, V.; Benítez, M.; Boudreault, P. -L; Buil, M. L.; Esteruelas, M. A.; Oñate, E.; Tsai, J. -y. Alkynyl Ligands as Building Blocks for the Preparation of Phosphorescent Iridium(III) Emitters: Alternative Synthetic Precursors and Procedures. INORGANIC CHEMISTRY. 2022. DOI: 10.1021/acs.inorgchem.2c00197

  • Benítez, María; Buil, María L.; Esteruelas, Miguel A.; Izquierdo, Susana; Oñate, Enrique; Tsai, Jui-Yi. Acetylides for the preparation of phosphorescent iridium(iii) complexes: iridaoxazoles and their transformation into hydroxycarbenes and N,C(sp3),C(sp2),O-Tetradentate ligands. INORGANIC CHEMISTRY. 2022. DOI: 10.1021/acs.inorgchem.2c03522

  • Buil M.L.; Collado A.; Esteruelas M.A.; Gomez-Gallego M.; Izquierdo S.; Iglesias Nicasio A.; Oñate E.; Sierra M.A. Preparation and degradation of rhodium and iridium diolefin catalysts for the acceptorless and base-free dehydrogenation of secondary alcohols. ORGANOMETALLICS. 2021. DOI: 10.1021/acs.organomet.1c00068

  • Buil M.L.; Cabeza J.A.; Esteruelas M.A.; Izquierdo S.; Laglera-Gándara C.J.; Nicasio A.I.; Oñate E. Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid. INORGANIC CHEMISTRY. 2021. DOI: 10.1021/acs.inorgchem.1c02893

  • Buil Juan, Ml; Esteruelas Rodrigo, Ma; López de Lama, Am. Recent Advances in Synthesis of Molecular Heteroleptic Osmium and Iridium Phosphorescent Emitters. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2021. DOI: 10.1002/ejic.202100663

  • Buil, María L.; Esteruelas, Miguel A.; Oñate, Enrique; Picazo, Nieves R. Dissimilarity in the Chemical Behavior of Osmaoxazolium Salts and Osmaoxazoles: Two Different Aromatic Metalladiheterocycles. ORGANOMETALLICS. 2021. DOI: 10.1021/acs.organomet.1c00621

  • Buil, M.L.; Esteruelas, M.A.; Izquierdo, S.; Nicasio, A.I.; Oñate, E. N-H and C-H Bond Activations of an Isoindoline Promoted by Iridium- And Osmium-Polyhydride Complexes: A Noninnocent Bridge Ligand for Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols. ORGANOMETALLICS. 2020. DOI: 10.1021/acs.organomet.0c00316

  • Buil Juan, María Luisa; Esteruelas, Miguel. A.; Gay, M. Pilar.; Gómez-Gallego, Mar; Nicasio A. I.; Oñate, E.; Santiago, A.; Sierra, Miguel A. Osmium Catalysts for Acceptorless and Base-Free Dehydrogenation of Alcohols and Amines: Unusual Coordination Modes of a BPI Anion. ORGANOMETALLICS. 2018. DOI: 10.1021/acs.organomet.7b00906

  • Buil, M. L.; Cardo, Juan J. F.; Esteruelas, Miguel A.; Fernández, Israel; Oñate, Enrique. An Entry to Stable Mixed Phosphine-Osmium-NHC Polyhydrides. INORGANIC CHEMISTRY. 2016. DOI: 10.1021/acs.inorgchem.6b00658

  • Buil, M. L.;Cardo, J. J. F.;Esteruelas, M. A.;Oñate, E. Dehydrogenative Addition of Aldehydes to a Mixed NHC-Osmium-Phosphine Hydroxide Complex: Formation of Carboxylate Derivatives. ORGANOMETALLICS. 2016. DOI: 10.1021/acs.organomet.6b00396

  • Buil, M.L.; Cardo, J.J.F.; Esteruelas, M.A.; Oñate, E. Square-Planar Alkylidyne-Osmium and Five-Coordinate Alkylidene-Osmium Complexes: Controlling the Transformation from Hydride-Alkylidyne to Alkylidene. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2016. DOI: 10.1021/jacs.6b05825

  • Buil, M.L.; Cardo, J.J.F.; Esteruelas, M.A.; Fernández, I.; Oñate, E. Hydroboration and hydrogenation of an osmium-carbon triple bond: Osmium chemistry of a bis-s-borane. ORGANOMETALLICS. 2015. DOI: 10.1021/om501274x

  • Buil, María L.; Cardo, Juan J. F.; Esteruelas, Miguel A.; Fernández, Israel; Oñate, Enrique. Unprecedented Addition of Tetrahydroborate to an Osmium-Carbon Triple Bond. ORGANOMETALLICS. 2014. DOI: 10.1021/om500451x

  • Buil, María L.; Esteruelas, Miguel A.; Herrero, J.; Izquierdo, S. ;Pastor, Isidro M.; Yus, M. Osmium catalyst for the borrowing Hydrogen Methodology: a-Alkylation of Arylacetonitriles and methyl Ketones. ACS CATALYSIS. 2013. DOI: 10.1021/cs4005375

  • Niembro,S.;Donnici,S.;Shafir,A.;Vallribera,A.;Buil,M. L.;Esteruelas,M. A.;Larramona,C. Perfluoro-tagged rhodium and ruthenium nanoparticles immobilized on silica gel as highly active catalysts for hydrogenation of arenes under mild conditions. NEW JOURNAL OF CHEMISTRY. 2013. DOI: 10.1039/c2nj40859g

  • Buil, M. L.;Esteruelas, M. A.;Fernández, I.;Izquierdo, S.;Oñate, E. Cationic dihydride boryl and dihydride silyl osmium(IV) NHC complexes: A marked diagonal relationship. ORGANOMETALLICS. 2013. DOI: 10.1021/om400188z

  • Buil,M. L.;Cadierno,V.;Esteruelas,M. A.;Gimeno,J.;Herrero,J.;Izquierdo,S.;Oñate,E. Selective hydration of nitriles to amides promoted by an Os-NHC catalyst: Formation and X-ray characterization of κ 2-amidate intermediates. ORGANOMETALLICS. 2012. DOI: 10.1021/om3006799

  • Buil, M. L.;Esteruelas, M. A.;Garcés, K. ;Oñate, E. From tetrahydroborate- to aminoborylvinylidene-osmium complexes via alkynyl-aminoboryl intermediates. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2011. DOI: 10.1021/ja109691v

  • Buil, M. L.;Castarlenas, R.;Esteruelas, M. A.;Izquierdo, S.;Lalrempuia, R. ;Oñate, E. Dicationic alkylidene, olefin and alkoxyalkenylcarbene, osmium complexes stabilized by a NHC Ligand. ORGANOMETALLICS. 2010

  • Buil, M. L.; Esteruelas, M. A.; Niembro, S.; Oliván, M.; Orzechowski, L.; Pelayo, C.; Vallribera, A. Dehalogenation and Hydrogenation of Aromatic Compounds Catalyzed by Nanoparticles Generated from Rhodium Bis(imino)pyridine Complexes. ORGANOMETALLICS. 2010. DOI: 10.1021/om1003072

  • Bolaño, T.; Buil, M. L.; Esteruelas, M. A.; Izquierdo, S.; Lalrempuia, R.; Oliván, M.; Oñate, E. C-C Bond Activation of the NHC Ligand of an Osmium-Amido Complex. ORGANOMETALLICS. 2010

  • Buil, M. L.; Esteruelas, M. A.; Garces, K.; Garcia-Raboso, J.; Olivan, M. Trapping of a 12-Valence-Electron Osmium Intermediate. ORGANOMETALLICS. 2009. DOI: 10.1021/om9002544

  • Buil, M. L.;Esteruelas,M. A.;Garces,K.;Oñate,E. Osmium-Alkenylearbyne and -Alkenylcarbene Complexes with an Steroid Skeleton: Formation of a Testosterone Organometallic Derivative Containing the 7H-Amino Adenine Tautomer. ORGANOMETALLICS. 2009

  • Buil, M.L.; Esteruelas,M. A.; Garces, K.; Olivan, M.; Oñate, E. C-Beta(Sp(2))-H Bond Activation of Alpha,Beta-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized Alpha-Substituted Pyridine Ligands. ORGANOMETALLICS. 2008. DOI: 10.1021/om800439g

  • Buil, M. L.; Esteruelas, M. A.; Garces, K.; Olivan, M.; Oñate, E. Understanding the Formation of N-H Tautomers from -Substituted Pyridines: Tautomerization of 2-Ethylpyridine Promoted by Osmium. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2007. DOI: 10.1021/ja073673r

  • Buil, M. L.;Esteruelas,M. A.;Lopez,A. M.;Mateo,A. C.;Oñate,E. Preparation and X-Ray Structures of Alkyl-Titanium(IV) Complexes Stabilized by Indenyl Ligands with a Pendant Ether Or Amine Substituent and their use in the Catalytic Hydroamination of Alkynes. ORGANOMETALLICS. 2007

  • Buil,M. L.;Esteruelas,M. A.;Lopez,A. M.;Mateo,A. C. Preparation of half-sandwich alkyl-titanium(IV) complexes stabilized by a cyclopentadienyl ligand with a pendant phosphine tether and their use in the catalytic hydroamination of aliphatic and aromatic alkynes. ORGANOMETALLICS. 2006

  • Buil,M. L.;Esteruelas,M. A.;Goñi,E.;Olivan,M.;Oñate,E. Displacement of phenyl and styryl ligands by benzophenone imine and 2-vinylpyridine on ruthenium and osmium. ORGANOMETALLICS. 2006

  • Baya, Miguel;Buil, Maria L.;Esteruelas, Miguel A.;Oñate, Enrique. Ene-type reactions between an alpha-alkenylphosphine and terminal alkynes promoted by osmmm-cyclopentadienyl fragments. ORGANOMETALLICS. 2005

  • Baya, Miguel;Buil, Maria L.;Esteruelas, Miguel A.;Oñate, Enrique. The cyclopentadienyl-osmium moiety as template for the formation of a dihydronaphthylphosphine by coupling between phenylacetylene and an alpha-alkenylphosphine. ORGANOMETALLICS. 2005

  • Baya, Miguel;Buil, Maria L.;Esteruelas, Miguel A.;Onate, Enrique. Dehydrogenation of a Coordinated Alkylphosphine as a method to Prepare Cyclopentadienyl-alpha-alkenylphosphine-osmium Complexes. ORGANOMETALLICS. 2004

  • Asensio, Adriana;Buil, Maria L.;Esteruelas, Miguel A.;Oñate, Enrique. A four-electron piT-alkyne complex as precursor for allenylidene derivatives: Preparation, structure, and reactivity of [ Os(eta**5- C//5H//5)(C=C=CPh//2)L(P**iPr //3)] PF//6 (L = CO, PHPh//2). ORGANOMETALLICS. 2004

  • Buil, M. L.;Esteruelas, M. A.;Lopez, A. M.;Oñate, E. Preparation and Characterization of 4-Azoniaheptatrienyl, 4-Azaheptatrienyl, Ruthenapyrrolinone, and Pyrrolinyl Complexes of Ruthenium. ORGANOMETALLICS. 2003

  • Buil, M. L.;Esteruelas, M. A.;Lopez, A. M.;Oñate, E. C-N and C-C Coupling Reactions: Preparation of New N-Heterocyclic Ruthenium Derivatives. ORGANOMETALLICS. 2003

  • Baya, Miguel;Buil, Maria L.;Esteruelas, Miguel A.;Lopez, Ana M.;Onate, Enrique;Rodriguez, J. Ramon. Regioselective Addition of Dienes to the C.beta.-C.gamma. Double Bond of the Allenylidene Ligand of [Ru(.eta.5-C5H5)(:C:C:CPh2)(CO)(PiPr3)]BF4. ORGANOMETALLICS. 2002

  • Buil, M.L.; Esteruelas, M.A.; Garcia-Yebra, C.; Gutierrez-Puebla, E.; Olivan, M. Hydride-Hydroxyosmacyclopropene Versus Hydride-Hydroxycarbyne and Cyclic Hydroxycarbene - Influence of the Substituents at the C(Oh) Carbon-Atom of the Carbon Donor Ligand. ORGANOMETALLICS. 2000. DOI: 10.1021/om9909542

  • Buil, M. L.; Eisenstein, O.; Esteruelas, M. A.; Garcia-Yebra, C.; Gutierrez-Puebla, E.; Olivan, M.; Onate, E.; Ruiz, N.; Tajada, M. A. Reactions of new osmium-dihydride complexes with terminal alkynes: Metallacyclopropene versus metal-carbyne. Influence of the alkyne substituent. ORGANOMETALLICS. 1999. DOI: 10.1021/om990426q

  • Buil, M. L.;Esteruelas, M. A. Synthesis and characterization of ruthenium-osmium complexes containing mu-bisalkenyl, mu-alkenylvinylidene, and mu-alkenylcarbene bridge ligands. ORGANOMETALLICS. 1999

  • Bohanna, C.;Buil, M. L.;Esteruelas, M. A.;Oñate, E.;Valero, C. C-C coupling of the alkynyl and alkenyl fragments of Os(C2CO2CH3){CH=CHC(O)OCH3}(CO)((PPr3)-Pr-i)(2) by action of HCl: The vinylidene [Os{CH=CHC(O)OCH3}(C=CHCO2CH3)(CO)((PPr3)-Pr-i)(2)] BF4 as intermediate. ORGANOMETALLICS. 1999

  • Buil, M. L.;Esteruelas, M. A.;Modrego, J.;Onate, E. Synthesis and characterization of (PPr3i)(2)(CO)HRu(mu-H)-(mu-OMe)Ir(cod): an unusual example of a heterometallic complex containing a mixed hydrido-alkoxide bridge. NEW JOURNAL OF CHEMISTRY. 1999

  • Aspley, C. J. ; Boxwell,C. ; Buil, M. L. ; Higgittt, C. L. ;Long, C. ;Perutz, R. N. New Combination of Donor and Acceptor: Bis(n6-benzene)chromium and hexafluorobenzene Form a Charge-Transfer Stacked Crystal. CHEMICAL COMMUNICATIONS. 1999

  • Buil, M. L.;Esteruelas, M. A.;Onate, E.;Ruiz, N. H - H interaction in four-membered P-H - H-M (M=osmium, ruthenium) rings. ORGANOMETALLICS. 1998

  • Albeniz, M. J.;Buil, M. L.;Esteruelas, M. A.;Lopez, A. M. Reactions of OsH2(eta(2)-CH2=CHEt)(CO)(P;Pr-i(3))(2) with unsaturated organic molecules. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 1997

  • Buil, M. L.;Esteruelas, M. A.;Lopez, A. M.;Onate, E. The Os(CO)((PPr3)-Pr-i)(2) unit as a support for the transformation of two alkyne molecules into new organometallic ligands. ORGANOMETALLICS. 1997

  • Buil, M. L.;Elipe, S.;Esteruelas, M. A.;Onate, E.;Peinado, E.;Ruiz, N. Five-coordinate complexes MHCl(CO)((PPr3)-Pr-i)(2) (M = Os, Ru) as precursors for the preparation of new hydrido- and alkenyl-metallothiol and monothio-beta-diketonato derivatives. ORGANOMETALLICS. 1997

  • Buil, M. L.;Espinet, P.;Esteruelas, M. A.;Lahoz, F. J.;Lledos, A.;Martinezilarduya, J. M.;Maseras, F.;Modrego, J.;Onate, E.;Oro, L. A.;Sola, E.;Valero, C. Oxidative addition of group 14 element hydrido compounds to OsH2(eta(2)-CH2=CHEt)-(CO)(P(i)Pr3)(2): Synthesis and characterization of the first trihydrido-silyl, trihydrido-germyl, and trihydrido-stannyl derivatives of osmium(IV). INORGANIC CHEMISTRY. 1996

  • Buil, M. L.;Esteruelas, M. A.;Lahoz, F. J.;Oñate, E.;Oro, L. A. Synthesis and Structure of Ru(ph(6)sn(3)(mu-Ome)(2)))(eta(2)-H-2)(co)(ppr(i)3) Containing a Tridentate Tin Donor Ligand and Coordinated Dihydrogen. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1995

  • Albeniz, M. J.;Buil, M. L.;Esteruelas, M. A.;Lopez, A. M.;Oro, L. A.;Zeier, B. Synthesis and Protonation of the Dithioformato Complex Osh(eta(2)-S2ch)(co)(pipr(3))(2). ORGANOMETALLICS. 1994



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