Perfil (CV) del personal docente investigador

Casas del Pozo, José María
Departamento: Departamento de Química Inorgánica
Área: Química Inorgánica
Centro: Facultad de Ciencias

Research Institute: INSTITUTO DE SÍNTESIS QUÍMICA Y CATÁLISIS HOMOGÉNEA (ISQCH)
Grupo: E17_23R: QUIMICA INORGÁNICA Y DE LOS COMPUESTOS ORGANOMETÁLICOS

Códigos UNESCO
  • Compuesto de coordinación
  • Compuestos organometálicos
  • Estructura de los compuestos inorgánicos

Tramos de investigación
  • CNEAI research evaluation. 01/01/23
  • CNEAI knowledge transfer evaluation. 01/01/19
  • CNEAI research evaluation. 01/01/17
  • CNEAI research evaluation. 01/01/11
  • CNEAI research evaluation. 01/01/05
  • CNEAI research evaluation. 01/01/99
  • CNEAI research evaluation. 01/01/98
Categoría profesional: Cated. Universidad

Cargos
  • Director del Servicio General de Apoyo a la Investigación
Correo electrónico: casas@unizar.es
ORCID: 0000-0003-0341-7699

Líneas de investigación
  • Química organometálica
  • Química de los elementos de transición
  • Antitumorales
  • Ingeniería cristalina
  • Clusters y compuestos con enlace metal-metal

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Artículos

  • Gimeno-Prat, A.; Martín, A.; Baya, M.; Casas, J. M. Trans-amidate platinum complexes anchoring water and N-donor molecules. The importance of hydrogen bonding. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2022. DOI: 10.1002/ejic.202200163

  • Pérez-Bitrián A.; Baya M.; Casas J.M.; Martín A.; Menjón B. Hydrogen bonding to metals as a probe for an inverted ligand field. DALTON TRANSACTIONS. 2021. DOI: 10.1039/d1dt00597a

  • Casas, J.M.; Diosdado, B.E.; Fornies, J.; Garcia-Monforte, M.A.; Laporta, R.; Martin, A.; Tomas, M. Synthesis and characterization of binuclear Pt(IV) complexes and tetranuclear mixed valence complexes of Platinum(II)-Platinum(IV). JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2019. DOI: 10.1016/j.jorganchem.2019.06.034

  • Pérez-Bitrián, A.; Baya, M.; Casas, J.M.; Martín, A.; Menjón, B.; Orduna, J. An Organogold(III) Difluoride with a trans Arrangement. ANGEWANDTE CHEMIE (INTERNATIONAL ED.). 2018. DOI: 10.1002/anie.201802379

  • Gimeno-Prat, Antonio; Cortés-Sanchón, Adrián; Martín, Antonio; Baya, Miguel; Casas, José M. Platinum-mediated monohydration of SO2. DALTON TRANSACTIONS. 2018. DOI: 10.1039/C8DT04169E

  • Pérez-Bitrián, A.; Baya, M.; Casas, J.M.; Falvello, L.R.; Martín, A.; Menjón, B. (CF3)3Au as a Highly Acidic Organogold(III) Fragment. CHEMISTRY - A EUROPEAN JOURNAL. 2017. DOI: 10.1002/chem.201703352

  • Pérez-Bitrián, A.; Martínez-Salvador, S.; Baya, M.; Casas, J.M.; Martín, A.; Menjón, B.; Orduna, J. Anionic Derivatives of Perfluorinated Trimethylgold. CHEMISTRY - A EUROPEAN JOURNAL. 2017. DOI: 10.1002/chem.201700927

  • Sicilia, V.;Borja, P.;Baya, M.;Casas, J. M. Selective turn-off phosphorescent and colorimetric detection of mercury(ii) in water by half-lantern platinum(ii) complexes. DALTON TRANSACTIONS. 2015. DOI: 10.1039/c5dt00087d

  • Sicilia,V.;Borja,P.;Casas,J. M.;Fuertes,S.;Martín,A. Selective synthesis of new half-lantern benzoquinolate platinum complexes. DFT and photophysical studies on the platinum (II,II) derivative. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2013. DOI: 10.1016/j.jorganchem.2013.01.027

  • Forniés, J.;Sicilia, V.;Borja, P.;Casas, J. M.;Díez, A.;Lalinde, E.;Larraz, C.;Martín, A.;Moreno, M. T. Luminescent benzoquinolate-isocyanide platinum(II) complexes: Effect of PtPt and  interactions on their photophysical properties. CHEMISTRY-AN ASIAN JOURNAL. 2012. DOI: 10.1002/asia.201200585

  • Sicilia,V.; Forniés,J.; Casas,J. M.; Martín,A.; López,J. A.; Larraz,C.; Borja,P.; Ovejero,C.; Tordera,D.; Bolink,H. Highly luminescent half-lantern cyclometalated platinum(II) complex: Synthesis, structure, luminescence studies, and reactivity. INORGANIC CHEMISTRY. 2012. DOI: 10.1021/ic201910t

  • Forniés, J.;Sicilia, V.;Casas, J. M.;Martín, A.;López, J. A.;Larraz, C.;Borja, P. ;Ovejero, C. Pt-Ag clusters and their neutral mononuclear Pt(ii) starting complexes: Structural and luminescence studies. DALTON TRANSACTIONS. 2011. DOI: 10.1039/c0dt01451f

  • Casas, J. M.;García, M. P.;Sanz, M.;Cacho, F. ;Pérez, J. 31P NMR spectroscopic studies of the influence of the environment in the degradation process of the Graham's salt. CERAMICS INTERNATIONAL. 2010

  • Casas, J.M.; García, M.P.; Sanz , M.; Cacho, F. ; Pérez, J. 31P NMR spectroscopic studies of the influence of the environment in the degradation process of the Graham's salt. INTERNATIONAL CERAMICS. 2010. DOI: 10.1016/j.ceramint.2009.06.028

  • Casas, J. M.;Diosdado,B. E.;Fornies,J.;Martin,A.;Rueda,A. J.;Orpen,A. G. Synthesis of Binuclear Platinum Complexes Containing the Ligands 8-Naphthyridine, 2-Aminopyridine, and 7-Azaindolate. an Experimental Study of the Steric Hindrance of the Bulky Pentafluorophenyl Ligands in the Synthesis of Binuclear Complexes. INORGANIC CHEMISTRY. 2008

  • Casas, J. M.;Fornies,J.;Fuertes,S.;Martin,A.;Sicilia,V. New Mono- and Polynuclear Alkynyl Complexes Containing Phenylacetylide as Terminal Or Bridging Ligand. X-Ray Structures of the Compounds NBu 4[Pt(CH2C6H4P(o-Tolyl) 2-kC,P)(C=CPh)2], [Pt(CH2C 6H4P(o-Tolyl)2-kC,P)(C=CPh)(CO)], [{Pt(CH2C6H4P(o-... ORGANOMETALLICS. 2007

  • Casas, J. M.;Diosdado, B. E.;Falvello, L. R.;Fornies, J.;Martin, A. Synthesis and in Solution and Solid State Structural Study of Intramolecular Pt Center Dot Center Dot Center Dot H Interactions in Pentafluorophenyl Platinum(Ii) Complexes Containing the Ligands Triazene, Formamidine, and 2-Aminopyridine. INORGANIC CHEMISTRY. 2005

  • Casas, Jose M.;Diosdado, Beatriz E.;Falvello, Larry R.;Fornies, Juan;Martin, Antonio;Rueda, Angel J. Hydrogen-bond mediation of supramolecular aggregation in neutral bis-(C//6F//5)Pt complexes with aromatic H-bond donating ligands. A synthetic and structural study. DALTON TRANSACTIONS. 2004

  • Casas, Jose M.;Fornies, Juan;Martin, Antonio;Rueda, Angel J. Synthesis of a Dinuclear Platinum-Silver Complex Containing a Reactive Acetone Imine Prepared in Situ from Acetone and Ammonia and Stabilized by Metal Complexation. ORGANOMETALLICS. 2002

  • Alonso, Ester; Casas, José María; Forniés, Juan; Fortuño, Consuelo; Martín, Antonio; Guy Orpen, A.; Tsipis, Constantinos A.; Tsipis, Athanassios C. Synthesis of Homo- or Hetero-trinuclear Palladium (II)/ Platinum(II) Compounds with Bridging Phosphido Ligands. Crystal and Electronic Structures (DFT) of [N(PPh3)2]2[Pt3(µ-PPh2)4(C6F5)4] and of Its Oxidation Product [Pt3(C6F5)4(µ-PPh2)4]. ORGANOMETALLICS. 2001. DOI: 10.1021/om010407s

  • Casas, J.M.;Falvello, L.R.;Fornies, J.;Gomez, J.;Rueda, A. Synthesis and Structural Characterization of the Luminescent Tetranuclear Complex (Nbu4)(2)((C6F5)(6)(Mu-Oh)(3)Pt3Hgcl) with Pt-Hg Bonds Unsupported by Covalent Bridging Ligands. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2000

  • Casas, J. M.;Falvello, L. R.;Fornies, J.;Mansilla, G.;Martin, A. Synthesis and structural characterization of platinum and palladium complexes containing O-donor C6X2O42- ligands. POLYHEDRON. 1999

  • Alonso, E.; Casas, J. M.; Cotton, F. A.; Feng, X. J.; Fornies, J.; Fortuño, C.; Tomas, M. Synthesis and crystal and electronic structures of the dinuclear platinum compounds [PEtPh3](2)[Pt-2(mu-PPh2)(2)(C6F5)(4)] and [Pt-2(mu-PPh2)(2)(C6F5)(4)]: A computational study by density functional theory. INORGANIC CHEMISTRY. 1999. DOI: 10.1021/ic981437z

  • Casas, J. M.;Fornies, J.;Martinez, F.;Rueda, A. J.;Tomas, M.;Welch, A. J. Synthesis and reactivity of dinuclear complexes containing eta(2)-phenyl-metal interactions. Crystal structures of [NBu4][(C6F5)(3)Pt{mu-Ph2PCH2PPh(eta(2)-Ph)}Pt(C6F5)(2)] and [NBu4][(C6F5)(3)Pt(mu-dppm)Pt(C6F5)(2)(CO)]. INORGANIC CHEMISTRY. 1999

  • Casas, J. M.;Martin, A. Simple preparation of palladium(II) complexes and determination of their structures by infrared spectroscopy. JOURNAL OF CHEMICAL EDUCATION. 1997

  • Casas, J. M.;Fornies, J.;Martin, A. Ligand structural factors in the establishment of intramolecular Pt center dot center dot center dot H hydrogen-bridging interactions in pentafluorophenyl complexes of platinum. JOURNAL OF THE CHEMICAL SOCIETY. DALTON TRANSACTIONS. 1997

  • Casas, J. M.;Falvello, L. R.;Fornies, J.;Martin, A. Syntheses and Structures of the Complexes cis-[M(C(6)F(5))(2)(N&arcraise;X)] (M = Pd, Pt; N&arcraise;X = 2-Iodoaniline, 2-Benzoylpyridine) Containing N&arcraise;X Acting as a Didentate Chelating Ligand and Displaying I-->M or O-->M Interactions. INORGANIC CHEMISTRY. 1996

  • Casas, J. M.;Fornies, J.;Martin, A.;Menjon, B.;Tomas, M. Synthesis and X-ray structure of [NBu(4)][{Pt(C6F5)(2)}(2)(mu-C6F5)(2){mu-Ag(SC4H8)}] (SC4H8=tetrahydrothiophene). Evidence of the existence of intramolecular Ag center dot center dot center dot F interactions in solution and in the solid state. POLYHEDRON. 1996

  • Ara, I.;Casas, J. M.;Fornies, J.;Rueda, A. J. Synthesis and Reactivity of (Pentafluorophenyl)platinate(II) Complexes with Bridging 1,8-Naphthyridine (napy) and X Ligands (X = C(6)F(5), OH, Cl, Br, I, SPh). Crystal Structure of [NBu(4)][Pt(2)(&mgr;-napy)(&mgr;-OH)(C(6)F(5))(4)].CHCl(3). INORGANIC CHEMISTRY. 1996

  • Casas, J. M.;Falvello, L. R.;Fornies, J.;Martin, A.;Welch, A. J. Pentafluorophenyl complexes of platinum containing intramolecular Pt center dot center dot center dot H hydrogen bridging interactions. Crystal structures of [NBu(4)][Pt(C6F5)(3)(8-hydroxyquinaldine)] and [NBu(4)][Pt(C6F5)(3)(8-methylquinoline)]. INORGANIC CHEMISTRY. 1996

  • Casas, J. M.;Falvello, L. R.;Fornies, J.;Martin, A. Direct Ag-Pt-2 interactions in pentafluorophenyl A-frame complexes containing halide or OH- and bis(diphenylphosphino)methane (dppm) as bridging ligands. Crystal structures of [(C6F5)(2)Pt(mu-OH)(mu-dppm){Ag(PPh(3))}Pt(C6F5)(2)]center dot C7H8 and [(C6F5)(2)Pt(mu-SC4H8)(mu-dppm)Pt(C6F5)(2)]center do. INORGANIC CHEMISTRY. 1996

  • Casas, J. M.;Martin, A.;Oliva, J.;Tomas, M. Synthesis, Structure and Reactivity of Stable Dianionic Organometallic Complexes of Pt(iv) - Crystal-Structure of [Petph(3)](2)[cis-Pt(c6f5)(2)cl-4] and [Nbu(4)][mer-Pt(c6f5)(2)cl-3(nh2-P-C6h4ch3)]. INORGANICA CHIMICA ACTA. 1995

  • Casas, J. M.;Fornies, J.;Martin, A.;Menjon, B.;Tomas, M. Pentafluorophenylplatinum Complexes Containing Eta(1)-Aryl-Pt Or Eta(2)-Aryl-Pt Interactions - Crystal-Structure of Cis-[Pt(c6f5)(2)-((Nc5h4[ch(eta(2)-Ph)ph]-2)-Kappa-N)]center-Dot-0.5c(6) H(5)me. JOURNAL OF THE CHEMICAL SOCIETY. DALTON TRANSACTIONS. 1995

  • Casas, J. M.;Fornies, J.;Martin, A.;Orera, V. M.;Orpen, A. G.;Rueda, A. J. Synthesis, structural characterization, and spectroscopic studies of heterodimetallic [NBu(4)][(C6F5)(3)Pt(mu-Pb)(mu-X)Pt(C6F5)(3)] (X=Cl,OH) complexes. INORGANIC CHEMISTRY. 1995

  • Uson, R.;Fornies, J.;Tomas, M.;Martinez, F.;Casas, J. M.;Fortuño, C. Symmetrical Or Unsymmetric Cleavage of the Bridging System in [M(2)(mu-C6f5)(2)(c6f5)(4)](2-)(M(2)=pt-2, Pd-2 Or Ptpd) with 2,2'-Bipyridine Or 1,10-Phenanthroline - Molecular-Structure of [Ppn](2)[(c6f5)(3)pt(mu-Bpy)pt(c6f3)(3)] and [Nbu(4)][pt(c6f5)(3)(phen)]. INORGANICA CHIMICA ACTA. 1995

  • Uson, R.;Fornies, J.;Falvello, L. R.;Tomas, M.;Casas, J. M.;Martin, A.;Cotton, F. A. Synthesis and Structure of 2 Dinuclear Anionic Complexes, with Pt(iii)-Pt(iii) Bonds and Unprecedented (C6f4o)(2-) Or (C6f4(or)(2))(2-) (R=me, Et) Quinone-Like Bridging Ligands. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1994. DOI: 10.1021/ja00095a019

  • Casas, J. M.;Fornies, J.;Martin, A.;Menjon, B. Synthesis, Solid-State and Solution Structure, and Reactivity of Cis-[Pt(c6f5)2(nc5h4-2-Ch2c6h5)] - a Compound Displaying an Arene-Platinum Interaction. ORGANOMETALLICS. 1993

  • Uson, R.;Fornies, J.;Falvello, L. R.;Tomas, M.;Casas, J. M.;Martin, A. Synthesis and Structure of [Nbu4][pt2ag(mu-Sc4h8)2(c6f5)6], a Trinuclear Compound Displaying 2 Structurally Different Anions in the Solid-State. INORGANIC CHEMISTRY. 1993

  • Garcia, M. P.;Jimenez, M. V.;Oro, L. A.;Lahoz, F. J.;Casas, J. M.;Alonso, P. J. Paramagnetic Mononuclear Rhodium(ii) Organometallic Complexes - X-Ray Structure of [Rh(c6cl5)2(p(oph)3)2]. ORGANOMETALLICS. 1993

  • Uson, R.;Fornies, J.;Tomas, M.;Casas, J. M.;Cotton, F. A.;Falvello, L. R.;Feng, X. J. Synthesis and Structural Characterization of the Pt2(ii,iii) Complex (Nbu4)[(c6f5)2pt(mu-C6f5)2pt(c6f5)2] and the Pt2(iii,iii) Complex (Nbu4)[(c6f5)2pt(mu-C6f5cl)(mu-C6f5)pt(c6f5)2] - Novel Ligand Reactivity of a Bridging C6f5 Group. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1993

  • Casas, J. M.;Falvello, L. R.;Fornies, J.;Martin, A.;Tomas, M. Binuclear Pentafluorophenyl Complexes Containing Halide and. JOURNAL OF THE CHEMICAL SOCIETY. DALTON TRANSACTIONS. 1993

  • Uson, R.;Fornies, J.;Tomas, M.;Ara, I.;Casas, J. M. Synthesis and Molecular-Structure of Trinuclear [Trans-Pt(c6cl5)2((mu-Cl)agpph3)2]. POLYHEDRON. 1992

  • Casas J. M.; Chisholm M.H.; Sicilia M.V. ; Streib W.E. Imino-Ether Complexes of Platinum: cis-[PtCl2(NH=C(OR)Me2] and [PtCl4(NH=C(OR)Me2], where R=Me, Et and iPr. Preparation, Characterization and X-ray Structure for [PtCl2(NH=C(OiPr)Me2]2. POLYHEDRON. 1991

  • Uson, R.;Fornies, J.;Tomas, M.;Ara, I.;Casas, J. M.;Martin, A. Neutral and Anionic Binuclear Perhalogenophenyl Platinum Silver Complexes with Pt-]Ag Bonds Unsupported by Covalent Bridges - Molecular-Structures of ((Tht)(c6cl5)(c6f5)2- Ptag(pph3)), (Nbu4)((c6f5)4ptag(tht)) and (Nbu4)-(Cis-(C6cl5)2(c6f5)2ptag(tht)) (Tht = Tetrahydrothiophene). JOURNAL OF THE CHEMICAL SOCIETY. DALTON TRANSACTIONS. 1991

  • Casas J. M.; Cayton R. H. ; Chisholm M.H. Comments on the Substitutional Lability of the Dimetal Carboxylates of Molybdenum and Rhodium. Effects of M-M MO Configuration. INORGANIC CHEMISTRY. 1991

  • Uson, R.;Fornies, J.;Tomas, M.;Casas, J. M.;Fortuño, C. The 1st Structurally Characterized Complex Containing Bridging 2,2'-Bipyridine - Synthesis and X-Ray Crystal-Structure of (Ppn)2[pt(c6f5)3(mu-2,2'-Bipy)pt(c6f5)3]. POLYHEDRON. 1989

  • Uson, R.;Fornies, J.;Tomas, M.;Casas, J. M. A Novel Type of Anionic Cluster Containing a Pt4ag2 Core. ANGEWANDTE CHEMIE (INTERNATIONAL ED.). 1989

  • Uson, R.;Fornies, J.;Tomas, M.;Casas, J. M.;Navarro, R. Synthesis and Reactivity of Binuclear Homo-Metallic Or Hetero-Metallic Complexes [Nbu4]2[mm'(mu-C6f5)2(c6f5)4] (M = M' = Pd Or Pt, M = Pt, M' = Pd) with Bridging Pentafluorophenyl Groups. JOURNAL OF THE CHEMICAL SOCIETY. DALTON TRANSACTIONS. 1989

  • Uson, R.;Fornies, J.;Tomas, M.;Ara, I.;Casas, J. M. Binuclear and Trinuclear Ptag Complexes with Or without Pt-Ag Bonds - Molecular-Structure of [Pph3(c6cl5)clpt(mu-Cl)agpph3]. INORGANIC CHEMISTRY. 1989

  • Uson, R.;Fornies, J.;Tomas, M.;Casas, J. M.;Cotton, F. A.;Falvello, L. R.;Llusar, R. Synthesis, X-Ray Structure, and Reactivity of (Nbu4)2[pt2(mu-C6f5)2(c6f5)4].H2o and (Nbu4)[pt2ag(mu-C6f5)2(c6f5)4o(c2h5)2] - the 1st Complexes Containing Bridging Pentafluorophenyl Groups. ORGANOMETALLICS. 1988

  • Uson, R.;Fornies, J.;Tomas, M.;Casas, J. M.;Cotton, F. A.;Falvello, L. R. Heterotrinuclear Pt2ag Clusters with Pt-Ag Bonds Unsupported by Covalent Bridges - Molecular-Structures of (Nbu4)2[pt2(mu-Cl)2(c6f5)4] and (Nbu4)[pt2agcl2(c6f5)4o(c2h5)2]. INORGANIC CHEMISTRY. 1987

  • Cotton, F. A.;Falvello, L. R.;Uson, R.;Fornies, J.;Tomas, M.;Casas, J. M.;Ara, I. Heterobinuclear Ptag Compounds with Platinum Silver Bonds Unsupported by Covalent Bridges - Molecular-Structure of (C6f5)3(sc4h8)ptagpph3. INORGANIC CHEMISTRY. 1987

  • Uson, R.;Fornies, J.;Tomas, M.;Casas, J. M.;Cotton, F. A.;Falvello, L. R. Synthesis, Structure, and Reactivity of (Nbu4)x[pt(c6cl5)2(mu-Cl)2ag]x, a Novel Chain Polymeric Pt-Ag Compound - Structure of (Nbu4)[ptagcl2(c6cl5)2(pph3)] and [Pt(c6cl5)2(mu-Cl)2ag2(pph2me)2]. INORGANIC CHEMISTRY. 1986

  • Uson, R.;Fornies, J.;Tomas, M.;Casas, J. M.;Cotton, F. A.;Falvello, L. R. Synthesis and Molecular-Structure of (Nbu4)x[pt(c6cl5)2(mu-Cl)2ag]x - a Novel Chain Polymeric Compound. POLYHEDRON. 1986

  • Usón R.; Forniés J.; Tomás M.; Casas J.M.; Cotton F.A.; Falvello L. R. New Compounds with Platinum to Silver Bonds Unsupported by Covalent Bridges. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1985

Comunicaciones

  • Baya, M.; Pérez-Bitrián, A.; Martínez-Salvador, S.; Martín, A.; Casas, J.M.; Menjón, B.; Orduna, J. Gold(II) Trihalide Complexes from Organogold(III) Precursors. CHEMISTRY - A EUROPEAN JOURNAL. 2018. DOI: 10.1002/chem.201705509

  • Baya, Miguel; Pérez-Bitrián, Alberto; Martínez-Salvador, Sonia; Casas, José María; Menjón, Babil; Orduna, Jesús. Gold(I) Fluorohalides: Theory and Experiment. CHEMISTRY - A EUROPEAN JOURNAL. 2017. DOI: 10.1002/chem.201605655

  • Casas, J. M.;Falvello, L. R.;Fornies, J.;Martin, A.;Tomas, M. Neutral Pentafluorophenyl Platinum Complexes Showing Intramolecular Eta-1 Or Eta-2 Arene Interactions. ABSTRACTS OF PAPERS - AMERICAN CHEMICAL SOCIETY. 1992

  • Uson, R.;Fornies, J.;Tomas, M.;Casas, J. M.;Cotton, F. A.;Falvello, L. R.;Feng, X. J. Synthesis of Binuclear Pt(ii)-Pt(iii) and Pt(iii)-Pt(iii) Complexes with Planar Cores. ABSTRACTS OF PAPERS - AMERICAN CHEMICAL SOCIETY. 1992



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