Perfil (CV) del personal docente investigador

Herrerías Larripa, Clara Isabel
Departamento: Departamento de Química Orgánica
Área: Química Orgánica
Centro: Facultad de Ciencias

Research Institute: INSTITUTO DE SÍNTESIS QUÍMICA Y CATÁLISIS HOMOGÉNEA (ISQCH)
Grupo: E37_23R: Catálisis Heterogénea en Síntesis Orgánicas Selectivas
Categoría profesional: Prof. Titular Univ.

Cargos
  • Vicedecana de Infraestructuras y Servicios


 
         

Artículos

  • Dorado, Vicente; Herrerías, Clara I.; Fraile, José M. Sulfonic resins as catalysts for the oxidation of alcohols with H2O2/KBr. CATALYSTS. 2024. DOI: 10.3390/catal14010074

  • Dorado, V.; Herrerías, C. I.; Fraile, J. M. Catalytic hydrolysis of epoxyfatty esters with solid sulfonic acids. MOLECULAR CATALYSIS. 2023. DOI: 10.1016/j.mcat.2023.113282

  • Dorado, V.; Herrerías, C. I.; Fraile, J. M. Simple metal-free oxidative cleavage of 1,2-diols. TETRAHEDRON. 2023. DOI: 10.1016/j.tet.2023.133450

  • Dorado, V.; Herrerias, C. I.; Fraile, J. M. Synthesis of hydroxyfatty esters by sequential epoxidation-hydrogenolysis: Solvent effects. APPLIED CATALYSIS A-GENERAL. 2021. DOI: 10.1016/j.apcata.2021.118270

  • Bescós, A.; Herrerías, C.I.; Hormigón, Z.; Mayoral, J.A.; Salvatella, L. Theoretical insight on the treatment of ß-hexachlorocyclohexane waste through alkaline dehydrochlorination. SCIENTIFIC REPORTS (NATURE PUBLISHING GROUP). 2021. DOI: 10.1038/s41598-021-88060-7

  • Angulo, Beatriz; Fraile, José M.; Gil, Laura; Herrerías, Clara I. Comparison of chemical and enzymatic methods for the transesterification of waste fish oil fatty ethyl esters with different alcohols. ACS OMEGA. 2020. DOI: 10.1021/acsomega.9b03147

  • Dorado, Vicente; Gil, Lena; Mayoral, José A.; Herrerías, Clara I.; Fraile, José M. Synthesis of fatty ketoesters by tandem epoxidation-rearrangement with heterogeneous catalysis. CATALYSIS SCIENCE AND TECHNOLOGY. 2020. DOI: 10.1039/c9cy01899a

  • Angulo, B.; Herrerías, C.I.; Hormigón, Z.; Mayoral, J.A.; Salvatella, L. Copper-catalyzed cyclopropanation reaction of but-2-ene. JOURNAL OF MOLECULAR MODELING. 2018. DOI: 10.1007/s00894-018-3737-1

  • Angulo, B.; Fraile, J.M.; Gil, L.; Herrerías, C.I. Bio-Lubricants production from fish oil residue by transesterification with trimethylolpropane. JOURNAL OF CLEANER PRODUCTION. 2018. DOI: 10.1016/j.jclepro.2018.07.260

  • Peña Carrodeguas, L.; Cristòfol, À.; Fraile, J.M.; Mayoral, J.A.; Dorado, V.; Herrerías, C.I.; Kleij, A.W. Fatty acid based biocarbonates: Al-mediated stereoselective preparation of mono-, di- and tricarbonates under mild and solvent-less conditions. GREEN CHEMISTRY. 2017. DOI: 10.1039/c7gc01206c

  • Angulo, Beatriz; Fraile, José Martía; Herrerias, Clara Isabel; Mayoral Murillo, José Antonio. Challenging cyclopropanation reactions on non-activated double bonds of fatty acids. RSC ADVANCES. 2017. DOI: 10.1039/C7RA01017F

  • Fraile, J. M.; García, J. I.; Herrerías, C. I.; Pires, E. Synthetic Transformations for the Valorization of Fatty Acid Derivatives. SYNTHESIS-STUTTGART. 2017. DOI: 10.1055/s-0036-1588699

  • Angulo, B.; García, J. I.; Herrerías, C. I.; Mayoral, J. A.; Miñana, A. C. Polytopic bis(oxazoline)-based ligands for recoverable catalytic systems applied to the enantioselective Henry reaction. ORGANIC & BIOMOLECULAR CHEMISTRY. 2015. DOI: 10.1039/c5ob01033k

  • García, J. I.; García, J.; Herrerías, C. I.; Mayoral, J. A.; Miñana, A. C.; Sáenz, C. Polytopic bis(oxazoline)-based ligands for the development of recoverable catalytic systems applied to the cyclopropanation reaction. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2014. DOI: 10.1002/ejoc.201301510

  • Fraile, J. M.; García, N.; Herrerías, C. I. Support effect on stereoselectivities of vinylogous mukaiyama-michael reactions catalyzed by immobilized chiral copper complexes. ACS CATALYSIS. 2013. DOI: 10.1021/cs400743n

  • Herrerias, C.I.; Mayoral, J.A. Selectivity modulation through immobilization of chiral catalysts on nanostructured supports. RENDICONTI LINCEI-SCIENZE FISICHE E NATURALI. 2013. DOI: 10.1007/s12210-013-0237-1

  • Fraile,J. M.;Garcia,N.;Herrerias,C. I.;Mayoral,J. A. Integration of heterogeneous catalysts into complex synthetic routes: Sequential vs. one-pot reactions in a (Knoevenagel + Mukaiyama-Michael + hydrogenation + transesterification) sequence. CATALYSIS SCIENCE AND TECHNOLOGY. 2013. DOI: 10.1039/c2cy20442h

  • Fraile, J. M.;Garcãœa, N.;Herrerãœas, C. I.;Martãœn, M.;Mayoral, J. A. Heterogeneous catalysis for tandem mukaiyamamichael and hydrogenation reactions: One-pot vs sequential processes. ACS CATALYSIS. 2012. DOI: 10.1021/cs200518s

  • Angulo,B.;García,J. I.;Herrerías,C. I.;Mayoral,J. A.;Miñana,A. C. Bis(oxazoline)-based coordination polymers: A recoverable system for enantioselective Henry reactions. JOURNAL OF ORGANIC CHEMISTRY. 2012. DOI: 10.1021/jo3005974

  • Fraile,J. M.;Herrerías,C. I. CAFC9: 9th congress on catalysis applied to fine chemicals. PLATINUM METALS REVIEW. 2011. DOI: 10.1595/147106711X541688

  • García,J. I.;Herrerías,C. I.;López-Sánchez,B.;Mayoral,J. A.;Reiser,O. Polytopic oxazoline-based chiral ligands for cyclopropanation reactions: A new strategy to prepare highly recyclable catalysts. ADVANCED SYNTHESIS AND CATALYSIS. 2011. DOI: 10.1002/adsc.201100213

  • Fraile,J. M.;García,N.;Herrerías,C. I.;Mayoral,J. A. Scope and limitations of one-pot multistep reactions with heterogeneous catalysts: The case of alkene epoxidation coupled to epoxide ring-opening. CATALYSIS TODAY. 2011. DOI: 10.1016/j.cattod.2011.03.067

  • Fakhfakh, F.;Baraket, L.;Ghorbel, A.;Fraile, J. M.;Herrerías, C. I. ;Mayoral, J. A. Effect of support properties on the performance of silica-supported bis(oxazoline)-copper chiral complexes. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL. 2010

  • Aldea, L.;Fraile, J. M.;García-Marín, H.;García, J. I.;Herrerías, C. I.;Mayoral, J. A. ;Pérez, I. Study of the recycling possibilities for azabis(oxazoline)-cobalt complexes as catalysts for enantioselective conjugate reduction. GREEN CHEMISTRY. 2010

  • Fraile, J. M.; Garcia, J. I.; Herrerias, C. I.; Mayoral, J. A.; Pires, E.; Salvatella, L. Beyond Reuse in Chiral Immobilized Catalysis: The Bis(Oxazoline) Case. CATALYSIS TODAY. 2009. DOI: 10.1016/j.cattod.2008.07.010

  • Fraile, J. M.;Garcia,J. I.;Herrerias,C. I.;Mayoral,J. A.;Pires,E. Enantioselective Catalysis with Chiral Complexes Immobilized on Nanostructured Supports. CHEMICAL SOCIETY REVIEWS. 2009

  • Marcos, Rocio; Rodriguez-Escrich, Carles; Herrerias, Clara Isabel; Pericas, Miguel Ángel. Metal-Mediated Cyclization of Aryl and Benzyl Glycidyl Ethers: A Complete Scenario. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2008. DOI: 10.1021/ja8062887

  • Pericàs, Miquel A.; Herrerías, Clara I.; Solà, L. Fast and enantioselective production of 1-aryl-1-propanols through a single pass, continuous flow process. ADVANCED SYNTHESIS AND CATALYSIS. 2008. DOI: 10.1002/adsc.200800108

  • Fabra, M. J.;Fraile,J. M.;Herrerias,C. I.;Lahoz,F. J.;Mayoral,J. A.;Perez,I. Surface-Enhanced Stereoselectivity in Mukaiyama Aldol Reactions Catalyzed by Clay-Supported Bis(Oxazoline)-Copper Complexes. CHEMICAL COMMUNICATIONS. 2008

  • Herrerías, C. I.; Yao, X.; Li, Z.; Li, C. -J. Reactions of C-H bonds in water. CHEMICAL REVIEWS. 2007. DOI: 10.1021/cr050980b

  • Werner,H.;Herrerias,C. I.;Glos,M.;Gissibl,A.;Fraile,J. M.;Perez,I.;Mayoral,J. A.;Reiser,O. Synthesis of polymer bound azabis(oxazoline) ligands and their application in asymmetric cyclopropanations. ADVANCED SYNTHESIS AND CATALYSIS. 2006

  • Herrerías, Clara I.; Zhang T. Y.; Li, Chao-Jun. Catalytic oxidation of alcohols to carbonyl compounds by oxygen under solvent-free and transition metal-free conditions. TETRAHEDRON LETTERS. 2006. DOI: 10.1016/j.tetlet.2005.10.123

  • Fraile, J. M.;Garcia, J. I.;Herrerias, C. I.;Mayoral, J. A. The First Synthesis of Organic-Inorganic Hybrid Materials With Chiral Bis(Oxazoline) Ligands. CHEMICAL COMMUNICATIONS. 2005

  • Fraile, J. M.;Garcia, J. I.;Herrerias, C. I.;Mayoral, J. A.;Reiser, O.;Vaultier, M. The Importance of Complex Stability for Asymmetric Copper-Catalyzed Cyclopropanations in [Emim][Otf] Ionic Liquid: the Bis(Oxazoline)-Azabis(Oxazoline) Case. TETRAHEDRON LETTERS. 2004

  • Fraile, J. M.;Garcia, J. I.;Herrerias, C. I.;Mayoral, J. A.;Harmer, M. A. Bis(Oxazoline)-Copper Complexes Supported by Electrostatic Interactions: Scope and Limitations. JOURNAL OF CATALYSIS. 2004

  • Fraile, J. M.;Garcia, J. I.;Herrerias, C. I.;Mayoral, J. A.;Gmough, S.;Vaultier, M. Comparison of the Immobilization of Chiral Bis(Oxazoline)-Copper Complexes Onto Anionic Solids and in Ionic Liquids. GREEN CHEMISTRY. 2004

  • Fraile, J. M.;Garcia, J. I.;Herrerias, C. I.;Mayoral, J. A.;Reiser, O.;Socuellamos, A.;Werner, H. The Role of Binding Constants in the Efficiency of Chiral Catalysts Immobilized by Electrostatic Interactions: the Case of Azabis(Oxazoline)Copper Complexes. CHEMISTRY - A EUROPEAN JOURNAL. 2004

  • Burguete, M. I.;Diez Barra, E.;Fraile, J. M.;Garcia, J. I.;Garcia Verdugo, E.;Gonzalez, R.;Herrerias, C. I.;Luis, S. V.;Mayoral, J. A.;Sanchez Verdu, P. Improvement of Ligand Economy Controlled by Polymer Morphology: the Case of Polymer-Supported Bis(Oxazoline) Catalysts (Vol 12, Pg 1821, 2002). BIOORGANIC & MEDICINAL CHEMISTRY LETTERS. 2003

  • Cornejo, A.;Fraile, J. M.;Garcia, J. I.;Gil, M. J.;Herrerias, C. I.;Legarreta, G.;Martinez Merino, V.;Mayoral, J. A. Surface-Mediated Improvement of Enantioselectivity With Clay-Immobilized Copper Catalysts. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL. 2003

  • Diez Barra, E.; Fraile, J. M.; Garcia, J. I.; Garcia Verdugo, E.; Herrerias, C. I.; Luis, S. V.; Mayoral, J. A.; Sanchez Verdu, P.; Tolosa, J. Polymer Immobilization of Bis(Oxazoline) Ligands Using Dendrimers as Cross-Linkers. TETRAHEDRON: ASYMMETRY. 2003. DOI: 10.1016/S0957-4166(03)00074-0

  • Burguete, M. I.;Diez-Barra, E.;Fraile, J. M.;Garcia, J. I.;Garcia-Verdugo, E.;Gonzalez, R.;Herrerias, C. I.;Luis, S. V.;Mayoral, J. A. Improvement of ligand economy controlled by polymer morphology: The case of polymer-Supported bis(oxazoline) catalysts. BIOORGANIC & MEDICINAL CHEMISTRY LETTERS. 2002

  • Fraile Jm; Garcia Ji; Harmer Ma; Herrerias Ci; Mayoral Ja; Reiser O; Werner H. Immobilisation of bis(oxazoline)-copper complexes on clays and nanocomposites. Influence of different parameters on activity and selectivity. JOURNAL OF MATERIALS CHEMISTRY. 2002

  • Burguete m. I. ; Fraile j. M. ; Garcia j. I. ; Gil m. J. ; Herrerias c. I. ; Luis s. V. ; Martinez-Merino v. ; Mayoral j. A. Electrostatic vs. Covalent immobilization of bis(oxazoline) complexes. AFINIDAD. 2002

  • Fernandez, A. I.;Fraile, J. M.;Garcia, J. I.;Herrerias, C. I.;Mayoral, J. A.;Salvatella, L. Reversal of enantioselectivity by change of solvent with clay-immobilized bis(oxazoline)-copper catalysts. CATALYSIS COMMUNICATIONS. 2001

  • Fraile, J. M. ;Garcia, J. I. ;Herrerias, C. I. ;Mayoral, J. A. ;Carrie, D. ;Vaultier, M. Enantioselective cyclopropanation reactions in ionic liquids. TETRAHEDRON: ASYMMETRY. 2001

  • Fraile, J. M.;Garcia, J. I.;Harmer, M. A.;Herrerias, C. I.;Mayoral, J. A. Bis(oxazoline)-metal complexes immobilized by electrostatic interactions as heterogeneous catalysts for enantioselective Diels-Alder reactions. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL. 2001

  • Burguete Mi; Fraile Jm; García Ji; García-Verdugo E; Herrerías Ci; Luis Sv; Mayoral Ja. Bis(oxazoline)-copper complexes covalently bonded to insoluble support as catalysts in cyclopropanation reactions. JOURNAL OF ORGANIC CHEMISTRY. 2001

  • Fraile, Jose M.;Garcia, Jose I.;Herrerias, Clara I.;Mayoral, Jose A.;Carrie, Daniel;Vaultier, Michel. Corrigendum to "Enantioselective cyclopropanation reactions in ionic liquids": [Tetrahedron: Asymmetry 12 (2001) 1891-1894]. TETRAHEDRON: ASYMMETRY. 2001. DOI: 10.1016/S0957-4166(01)00392-5

Capítulos

  • Non-covalent immobilization Pires Ezquerra, María Elisabet. ENANTIOSELECTIVE HOMOGENEOUS SUPPORTED CATALYSIS. 2012

  • Non-covalent immobilization. Fraile, J. M.; García, J. I.; Herrerías, C. I.; Mayoral, J. A.; Pires, E. ENANTIOSELECTIVE HOMOGENEOUS SUPPORTED CATALYSIS. 2012

  • Green Bases in Water. Fraile, J.M.; Herrerías, C. I.; Mayoral, J. A. REACTIONS IN WATER “WATER AS A GREEN SOLVENT. 2010



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